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Advanced flow-reactor capabilities created at Cummins were applied to the study of the diesel particulate matter (soot) oxidation process. This approach complemented the on-engine studies with a number of important features, including accurate control of gas composition and soot layer temperature. Using the developed methodology for quantitative soot oxidation studies in a broad range of temperatures (200-700°C), an initial set of experiments was performed to compare the behavior of the real and model soot samples under the identical conditions (10%vol. of O2, 0-15%vol. of H2O). It was found that presence of H2O vapor synergistically enhances the rate of oxidation by O2 of the diesel soot sample. However, the behavior of the model soot sample (carbon black) was virtually not affected by H2O. Kinetic analysis of the obtained results revealed an unusual type of behavior, with the activation energy of soot oxidation increasing in the course of the experiment.

This paper examines the energy pathways of a 29cc air-cooled two-stroke engine operating on natural gas with different exhaust geometries. The engine was operated at wide-open-throttle at a constant speed of 5400 RPM with ignition adjusted to yield maximum brake torque while the fueling was adjusted to examine both rich and lean combustion. The exhaust configurations examined included an off-the-shelf (OTS) model and two other custom models designed on Helmholtz resonance theory. The custom designs included both single and multi-cone features. Out of the three exhaust systems tested, the model with maximum trapping efficiency showed a higher overall efficiency due to lower fuel short-circuiting and heat transfer. The heat transfer rate was shown to be 10% lower on the new designs relative to OTS model.

Beginning 2007, heavy-duty engine certification would require that in-use emissions from vehicles be measured under ‘real-world’ operating conditions using on-board measurement devices. An on-board portable emissions measurement system called Mobile Emissions Measurement System (MEMS) was developed at West Virginia University (WVU) to record in-use, continuous and brake-specific emissions from heavy-duty diesel-powered vehicles. The objective of this paper is to present a preliminary development of a test data quality assurance methodology for emissions measured using the any portable emissions measurement system (PEMS). The first stage of the methodology requires ensuring the proper operation of the different sensors and transducers during data collection. The second stage is data synchronization and pre-processing. The next stage is systematic checking of possible errors from transducers and sensors.

Performance of a natural gas two-stroke engine incorporated in a 1-kW free-piston oscillating Linear Engine Alternator (LEA) - a household electricity generator - was investigated under different resonant frequencies for pre-design phase purposes. To increase the robustness, power density, and thermal efficiencies, the crank mechanism in free-piston LEA is omitted and all moving parts of the generator operate at a fixed resonant frequency. Flexure springs are the main source of the LEA’s stiffness and the mass-spring dynamics dominates the engine’s speed. The trade-off between the engine’s performance, mass-spring system limits, and power and efficiency targets versus the LEA speed is very crucial and demands a careful investigation specifically at the concept design stages to find the optimum design parameters and operating conditions. CFD modeling was performed to analyze the effects of resonant frequency on the engine’s gas exchange behavior.

In August of 2011, the US Environmental Protection Agency issued new Green House Gas (GHG) emissions regulations for heavy duty vehicles. These regulations included new procedures for the evaluation of hybrid powertrains and vehicles. One of the hybrid options allows for the evaluation of an engine plus a hybrid transmission (a powertrain). For this type of testing, EPA has proposed simulating a vehicle following the hybrid vehicle test procedures, including the use of the vehicle cycles and the A to B comparison testing - as required for the full vehicle evaluation option. This paper proposes an alternative approach by defining a powertrain cycle. The powertrain cycle is based on the heavy duty engine emissions cycle - the transient FTP cycle. Simulation and test results are presented showing similar performance over the engine and vehicle cycles. This approach offers several advantages as compared to the procedure described in EPA's GHG rule.

Accumulation of lubricant and fuel derived ash in the diesel particulate filter (DPF) during vehicle operation results in a significant increase of pressure drop across the after-treatment system leading to loss of fuel economy and reduced soot storage capacity over time. Under certain operating conditions, the accumulated ash and/or soot cake layer can collapse resulting in ash deposits upstream from the typical ash plug section, henceforth termed mid-channel ash deposits. In addition, ash particles can bond (either physically or chemically) with neighboring particles resulting in formation of bridges across the channels that effectively block access to the remainder of the channel for the incoming exhaust gas stream. This phenomenon creates serious long-term durability issues for the DPF, which often must be replaced. Mid-channel deposits and ash bridges are extremely difficult to remove from the channels as they often sinter to the substrate.

Biodiesel is a promising alternative to traditional diesel fuel due to its similar combustion properties to diesel and lower carbon emissions on a well-to-wheel basis. However, combusting biodiesel still generates hydrocarbon (HC), CO, NOx and particulate matter (PM) emissions, similar to those from traditional diesel fuel usage. Therefore, aftertreatment systems will be required to reduce these emissions to meet increasingly stringent emission regulations to minimize the impact to the environment. Diesel oxidation catalysts (DOC) are widely used in modern aftertreatment systems to convert unburned HC and CO, to partially convert NO to NO2 to enhance downstream selective catalytic reaction (SCR) catalyst efficiency via fast SCR and to periodically clean-up DPF via controlled soot oxidation. In this work, we focus on the performance difference between biodiesel and diesel over a commercial DOC catalyst to identify the knowledge gap during the transition from diesel fuel to biodiesel.

The temporary deactivation of the selective catalytic reduction (SCR) device due to malfunction requires the engine control to engage multiple engine-out calibrations. Further, it is expected that emitted particles will be different in composition, size and morphology when an engine, which meets the 2010 particulate matter (PM) gravimetric limits, is programmed with multiple maps. This study investigated the correlation between SCR-out/engine-out PM emissions from an 11-liter Volvo engine. Measurement of PM concentrations and size distributions were conducted under steady state and transient cycles. Ion Chromatograph analysis on gravimetric filters at the SCR-out has revealed the presence of sulfates. Two different PM size-distributions were generated over a single engine test mode in the accumulation mode region with the aid of a design of experiment (DOE) tool. The SCR-out PM size distributions were found to correlate with the two engine-out distributions.

In-service 1994-2003 heavy-duty trucks were acquired by West Virginia University (WVU), equipped with the WVU Mobile Emissions Measurement System (MEMS) to measure on-road NOx, and driven on road routes near Sabraton, West Virginia, and extending up to Washington, PA to obtain real-world oxides of nitrogen (NOx) emissions data on highways and local roads. The MEMS measured 5Hz NOx, and load was obtained from the electronic control unit. Trucks were loaded to about 95% of their gross vehicle weights. Emissions in g/mi and g/bhp-hr were computed over the various road routes. In addition, some of the trucks were tested 1 to 2 years later to determine emission changes that may have occurred for these trucks. Emission results varied significantly over the different road routes due to different speeds, driving patterns, and road grades.

Dedicated natural gas engines suffer the disadvantages of limited vehicle range and relatively few refueling stations. A vehicle capable of operating on either gasoline or natural gas allows alternative fuel usage without sacrificing vehicle range and mobility. However, the bi-fuel engine must be made to provide equal performance on both fuels. Although bi-fuel conversions have existed for a number of years, historically natural gas performance is degraded relative to gasoline due to reduced volumetric efficiency and lower power density of CNG. Much of the performance losses associated with CNG can be overcome by increasing the compression ratio. However, in a bi-fuel application, high compression ratios can result in severe engine knock during gasoline operation. Variable intake valve timing, increased exhaust gas recirculation and retarded ignition timing were explored as a means of controlling knock during gasoline operation of a bi-fuel engine.

With the purpose of reducing emission level while maintaining the high torque character of diesel engine, various solutions have been proposed by researchers over the world. One of the most attractive methods is to use dual fuel technique with premixed gaseous fuel ignited by a relatively small amount of diesel. In this study, Methane (CH4), which is the main component of natural gas, was premixed with intake air and used as the main fuel, and diesel fuel was used as ignition source to initiate the combustion. By varying the proportion of diesel and CH4, the combustion and emissions characteristics of the dual fuel (diesel/CH4) combustion system were investigated. Different cases of CFD studies with various concentration of CH4 were carried out. A validated 3D quarter chamber model of a single cylinder engine (diesel fuel only) generated by using AVL Fire ESE was modified into dual fuel mode in this study.

Due to tightening emission legislations, both within the US and Europe, including concerns regarding greenhouse gases, next-generation combustion strategies for internal combustion diesel engines that simultaneously reduce exhaust emissions while improving thermal efficiency have drawn increasing attention during recent years. In-cylinder combustion temperature plays a critical role in the formation of pollutants as well as in thermal efficiency of the propulsion system. One way to minimize both soot and NOx emissions is to limit the in-cylinder temperature during the combustion process by means of high levels of dilution via exhaust gas recirculation (EGR) combined with flexible fuel injection strategies. However, fuel chemistry plays a significant role in the ignition delay; hence, influencing the overall combustion characteristics and the resulting emissions.

An operational challenge associated with SCR catalysts is the NH3 slip control, particularly for commercial small pore Cu-zeolite formulations as a consequence of their significant ammonia storage capacity. The desorption of NH3 during increasing temperature transients is one example of this challenge. Ammonia slipping from SCR catalyst typically passes through a platinum based ammonia oxidation catalyst (AMOx), leading to the formation of the undesired byproducts NOx and N2O. We have discovered a distinctive characteristic, an overlapping NH3 desorption and oxidation, in a state-of-the-art Cu-zeolite SCR catalyst that can minimize NH3 slip during temperature transients encountered in real-world operation of a vehicle.

Mitigation of ammonia slip from SCR system is critical to meeting the evolving NH₃ emission standards, while achieving maximum NOx conversion efficiency. Ammonia slip catalysts (ASC) are expected to balance high activity, required to oxidize ammonia across a broad range of operating conditions, with high selectivity of converting NH₃ to N₂, thus avoiding such undesirable byproducts as NOx or N₂O. In this work, new insights into the behavior of an advanced ammonia slip catalyst have been developed by using accelerated progressive catalyst aging as a tool for catalyst property interrogation. The overall behavior was deconstructed to several underlying functions, and referenced to an active but non-selective NH₃ oxidation function of a diesel oxidation catalyst (DOC) and to the highly selective but minimally active NH₃ oxidation function of an SCR catalyst.

This paper explores the feasibility of using in-cylinder pressure-based variables to predict gaseous exhaust emissions levels from a Navistar T444 direct injection diesel engine through the use of neural networks. The networks were trained using in-cylinder pressure derived variables generated at steady state conditions over a wide speed and load test matrix. The networks were then validated on previously “unseen” real-time data obtained from the Federal Test Procedure cycle through the use of a high speed digital signal processor data acquisition system. Once fully trained, the DSP-based system developed in this work allows the real-time prediction of NOX and CO2 emissions from this engine on a cycle-by-cycle basis without requiring emissions measurement.

Dual primary full-flow dilution tunnels represent an integral part of a heavy-duty transportable emissions measurement laboratory designed and constructed to comply with US Code of Federal Regulations (CFR) 40 Part 1065 requirements. Few data exist to characterize the evolution of particulate matter (PM) in full scale dilution tunnels, particularly at very low PM mass levels. Size distributions of ultra-fine particles in diesel exhaust from a naturally aspirated, 2.4 liter, 40 kW ISUZU C240 diesel engine equipped with a diesel particulate filter (DPF) were studied in one set of standard primary and secondary dilution tunnels with varied dilution ratios. Particle size distribution data, during steady-state engine operation, were collected using a Cambustion DMS500 Fast Particulate Spectrometer. Measurements were made at four positions that spanned the tunnel cross section after the mixing orifice plate for the primary dilution tunnel and at the outlet of the secondary dilution tunnel.

The high global warming potential of nitrous oxide (N₂O) led to its recent inclusion in the list of regulated pollutants under the emerging greenhouse gas regulations. While N₂O can be present in small quantities among the combustion products, it can also be generated as a minor byproduct in various types of aftertreatment systems. In this work, a systematic review of sources of N₂O is presented, along with the potential mechanisms of formation in a typical selective-catalytic-reduction-based diesel exhaust aftertreatment system. It is demonstrated that diesel oxidation catalysts (DOC), selective catalytic reduction (SCR) catalyst, and ammonia slip catalyst (ASC) can all potentially contribute to N₂O formation, depending on the catalyst material and exhaust gas conditions, as well as aftertreatment operation strategies. Furthermore, catalysts used in SCR aftertreatment system are also shown to decompose and/or reduce N₂O to N₂ under select conditions.

Evermore demanding market and legislative pressures require stationary lean burn natural gas engines to operate at higher efficiencies and reduced levels of emissions. Higher in-cylinder pressures and leaner air/fuel ratios are required in order to meet these demands. The performance and durability of spark plug ignition systems suffer as a result of the increase in spark energy required to maintain suitable engine operation under these conditions. Advancing the state of the art of ignition systems for these engines is critical to meeting increased performance requirements. Laser-spark ignition has shown potential to improve engine performance and ignition system durability to levels required meet or exceed projected requirements. This paper discusses testing which extends previous efforts [1] to include constant fueling knock, misfire, thermal efficiency, and NOx emissions mapping of a single cylinder lean burn natural gas engine.

The conversion of existing diesel engines to natural-gas operation can reduce the dependence on petroleum imports and curtail engine-out emissions. A convenient way to perform such conversion is by adding a gas injector in the intake manifold and replacing the diesel fuel injector with a spark plug to initiate and control the combustion process. However, challenges may appear with respect to engine’s efficiency and emissions as natural-gas spark-ignition combustion inside a diesel combustion chamber is different to that in conventional spark ignition engines. For example, major difference is the phasing and duration of the fast burn, defined as the period in which the rate of heat release increases linearly with crank angle. This study presents a methodology to investigate the fast burn inside a diesel geometry using heat release data.

The paper will discuss the design and development of heavy-duty diesel engines to meet the US EPA 2010 on-highway standards - 0.2 g/HP-hr NOx and 0.01 g/HP-hr particulate matter (PM). In meeting these standards a combination of in-cylinder control and aftertreatment control for both NOx and particulate has been used. For NOx control, a combination of cooled exhaust gas recirculation (EGR) and selective catalytic reduction (SCR) is used. The SCR catalyst uses copper zeolite to achieve high levels of NOx conversion efficiency with minimal ammonia slip and unparalleled thermal durability. For particulate control, a diesel particulate filter (DPF) with upstream oxidation catalyst (DOC) is used. While the DPF may be actively regenerated when required, it operates predominantly with passive regeneration - enabled by the high NOx levels between the engine and the DPF, associated with high efficiency SCR systems and NO₂ production across the DOC.